中国化学快报

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Solid-phase Synthesis of Diethyl Trans-1-Alkenephosphonates Using Polymerbound α-Diethoxyphosphoryl Methyl Selenide

Shou Ri SHENG, Xiao Ling LIU, Wei ZHOU, Xian HUANG

中国化学快报. 2005, 16(03): 285-286.

摘要 ( )

可视化

The solid-phase preparation of diethyl trans-1-alkenephosphonates via seleno-polymer reagent has been reported.

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The Benzoylation of 6-Methyluracil and 5-Nitro-6-methyluracil

Zhi Li ZHANG, Peng HAN, Xiao Yan MA, Jie LIU, Xiao Wei WANG, Jun Yi LIU

中国化学快报. 2005, 16(03): 287-289.

摘要 ( )

可视化

6-Methyluracil and 5-nitro-6-methyluracil react with variable molar quantities of benzoyl chloride in acetonitrile-pyridine at room temperature to give 1-N, 3-N-dibenzoyl-6-methyluracil 3b and 1-N-benzoyl-5-nitro-5-methyluracil 4b.The reactive rates of debenzoylation of 3b and 4b were investigated.

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Novel Phenomenon of Oxygen-to-oxygen Silyl Migration in Directed Aldol Reaction

Zhi Quan ZHAO, Li Zeng PENG, Yu Lin LI

中国化学快报. 2005, 16(03): 290-292.

摘要 ( )

可视化

The phenomenon of migration of the silyl groups from α-oxygen to β-oxygen in sodium aldol reaction was observed for the first time in this paper.

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A Green and Efficient Synthesis of Xanthenedione Derivatives Promoted by InCl₃·4H₂O in Ionic Liquid

Xue Yuan HU, Xue Sen FAN, Xin Ying ZHANG, Jian Ji WANG

中国化学快报. 2005, 16(03): 293-295.

摘要 ( )

可视化

Xanthenedione derivatives were prepared through InCl₃·4H₂O promoted condensation of aldehydes with 5, 5-dimethyl-1, 3-cyclohexandione in [bmim][BF₄]. The advantages of this method are: simple operation, environmental benign and high efficiency. Moreover, the reaction media and the catalyst can be recovered and reused effectively for at least six times.

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Pentaerythritol-based Carbosilane Dendrimers

Xin De TANG, Qi Zhen ZHANG, Qi Feng ZHOU

中国化学快报. 2005, 16(03): 296-298.

摘要 ( )

可视化

A series of novel pentaerythritol-based carbosilane dendrimers have been synthesized.Using pentaerythritol-based tetraallyl ether as core molecule, the dendrimers have been prepared up to the third generation with 108 allyl groups on the periphery by alternate allylation-hydrosilylation approach.

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The Synthesis of 2,4,6-Triisopropyl-1,3,5-trioxane Catalyzed by Ionic Liquids

Jian Guo YANG, Xin Yu YU, Hai Hong WU, Zhi Lin CHENG, Yue Ming LIU, Ming Yuan HE

中国化学快报. 2005, 16(03): 299-302.

摘要 ( )

可视化

The synthesis of 2, 4, 6-triisopropyl-1, 3, 5-trioxane with high yield and desirable selectivity from solvent-free cyclotrimerization of isobutyraldehyde catalyzed by ionic liquids was reported in this work.

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Synthesis of a New Porphyrin-fluorescein Hybrid and its Supramolecular Self-assembly with Amino-porphyrinatomanganese (Ⅲ) by Hydrogen-bonding

Jia Zheng LU, Jin Wang HUANG, Li Fen FAN, Jie LIU, Ke Zhuan XU, Xian Li CHEN, Liang Nian JI

中国化学快报. 2005, 16(03): 303-306.

摘要 ( )

可视化

A new porphyrin-fluorescein hybrid 2 (Fl-PPTPP) has been synthesized and characterized by UV-Vis, IR, ¹H-NMR, ESI-MS and elemental analysis. The supramolecular self-assembly of Fl-PPTPP with amino-porphyrinatomanganese(Ⅲ) [Mn^(Ⅲ) (p-APTPP)C1] by hydrogen-bonding was studied using fluorescence spectroscopic titration and ESI-MS.

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Unexpected Side Reaction in the Intermolecular N-H Insertion of Phenyl Diazoacetates with Arylamines

Yan Xin ZHU, Yuan Hua WANG, Zhi Yong CHEN, Wen Hao HU

中国化学快报. 2005, 16(03): 307-310.

摘要 ( )

可视化

Unexpected side reaction is discovered from the N-H insertion of phenyl diazoacetates with arylamines in the presence of Rh₂(OAc)₄ catalyst. This side reaction is not evident with copper catalysts such as Cu(acac)₂ or Cu(OTf)₂. Good yieldof the N-H insertion was obtained by using 0.2% of copper catalyst.

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Remarkable Stereoelectronic Effect of the Methylenedioxy Phenyl System in the Total Synthesis of Cephalotaxine

Hua YANG, Yong Qiang WANG, Wei Dong Z. LI

中国化学快报. 2005, 16(03): 311-314.

摘要 ( )

可视化

Methylenedioxyphenyl unit displays a significant stereoelectronic effect in some key transformations in the total synthesis of cephalotaxine. The ring-strain of methylenedioxy ring may account for some important facile ring-skeleton rearrangements.

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Poly{[4-(hydroxyl)(tosyloxyl)iodo]styrene} Promoted Halotosyloxylation Reaction of Alkynes

Jiang Min CHEN, Xiang Jin LIN, Lu Ling WU, Xian HUANG

中国化学快报. 2005, 16(03): 315-316.

摘要 ( )

可视化

Halotosyloxylation reaction of alkynes with iodine or NBS or NCS was efficiently promoted by the poly{[4-(hydroxyl)(tosoyloxyl)iodo]styrene}.

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Synthesis of N-Phosphoryl Branched Peptides

Jie YANG, Yu Yang JIANG, Sheng Li CAO, Hua FU, Yu Fen ZHAO

中国化学快报. 2005, 16(03): 317-320.

摘要 ( )

可视化

H-phosphonates were conveniently prepared by direct transesterification of diphenyl phosphite (DPP) with the corresponding alcohols, without further purification they were reacted with branched peptide methyl ester (L-Leu₂-L-LysOMe) through Atherton-Todd method, a series of different substituted alkyloxy (N-phosphoryl-L-Leu)₂-L-LysOMe were synthesized, and their structures were confirmed by ³¹P NMR, ESI-MS, ¹H NMR, ¹³C NMR, IR and elemental analysis.The approach possesses the advantages of easy operation, high yield and inexpensive phosphorylating reagent.

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Benzoin Condensation in Imidazolium Based Room-temperature Ionic Liquids

Fang Sheng JIANG, Hua YU, Ge GAO, Ru Gang XIE

中国化学快报. 2005, 16(03): 321-324.

摘要 ( )

可视化

Benzoin condensation promoted efficiently in three imidazolium based room temperature ionic liquids [bmim]Br,[bmim]BF₄ and [Bnmim]BF₄ is reported for the first time. Benzoins were obtained in up to 91% yield within less than 30 min under mild conditions.

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Stereoslective Synthesis of (Z)-1,2-Bis(arylseleno)-1-alkene by Addition of Cesium Arylselenolate to Alkynyl Selenide

Rui Liang LU, Xin Hua XU, Wen Qi LIU, Qiu Lin ZHANG, Xiong CHEN

中国化学快报. 2005, 16(03): 325-326.

摘要 ( )

可视化

Alkynyl selenide reacted with cesium arylselenolate in commercial THF at r.t under N₂ to afford (Z)-1, 2-bis(arylseleno)-1-alkene in high yields.

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Solventless Friedel-Crafts Acylation under Microwave Activation

Wei DENG, Yu XU, Qing Xiang GUO

中国化学快报. 2005, 16(03): 327-330.

摘要 ( )

可视化

A novel catalytic system, ZnCl₂ supported on alumina, was found to be an efficient and readily available medium for the solvent-free Friedel-Crafts acylation reactions under microwave irradiation. Good yields and high catalytic efficiencies were observed within short reaction times.Comparing with silica gel, alumina was more efficient under the same conditions.

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Asymmetric Intramolecular Cyclopropanation Induced by (β-Diketone)-copper Complex

Qing Fang CHENG, Xing You XU, Wei Xing MA, Tian Pa YOU

中国化学快报. 2005, 16(03): 331-334.

摘要 ( )

可视化

Asymmetric intramolecular cyclopropanation of allylic diazoacetate was investigated using a chiral (β-diketone)-copper complex as catalyst, excellent yield and enantioselectivity were achieved. Some factors influencing enantioselectivity were discussed.

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Preparation and Electrochemical Properties of 3-Pyridinyl-6-aryl-1,2,4-triazolo[3,4-b] [1,3,4]thiadiazoles

Tai XIAO, Hui Xue LI, Chun Xia TAN, Miao CHEN

中国化学快报. 2005, 16(03): 335-337.

摘要 ( )

可视化

A series of 3-pyridinyl-6-aryl-1, 2, 4-triazolo[3, 4-b] [1, 3, 4]thiadiazoles (PATT) were prepared, the structures were confirmed by IR and ¹H NMR spectra. The results of cyclic voltammetry measurements imply that all these compounds have a higher electron affinity (E_A) than 2-(4-biphenyl)-5-(4-tert-butyl phenyl)-1, 3, 4-oxadiazole (PBD) which implies that PATT could be acting as better electron acceptors than widely used electron transporting material PBD.

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Hydrogenation of SBS Catalyzed by Immobilized Ru-TPPTS Complex in Polyether Molten Salt

Li WEI, Jing Yang JIANG, Yan Hua WANG, Zi Lin JIN

中国化学快报. 2005, 16(03): 338-340.

摘要 ( )

可视化

Catalytic hydrogenation of SBS was performed for the first time in polyether molten salt with Ru/TPPTS complex as catalyst. Experimental results showed that the hydrogenation degree can be enhanced significantly by the addition of triphenylphosphine (TPP). When the molar ratio of TPP, TPPTS and Ru is 2:5:1, 89% hydrogenation degree can be achieved after 12 h under reaction conditions of 5.0 MPa and 150℃. The ionic liquid containing catalyst can be reused three times without obvious changes in the catalytic selectivity and activity.

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Synthesis and Spectral Properties of Novel Water-soluble Near-infrared Fluorescent Indocyanines

Li Qiu WANG, Xiao Jun PENG, Wei Bing ZHANG, Fei YIN, Jing Nan CUI, Xin Qin GAO

中国化学快报. 2005, 16(03): 341-344.

摘要 ( )

可视化

Two fluorescent pentamethine and a squarylium indocyanines containing at least one p-carboxybenzyl group on N atoms in the heterocyclic rings were synthesized. They had good water solubility and photostability. Their maximum absorption and maximum emission were 600-700 nm in water. When it was anchored onto nanostructured TiO₂ electrode, compared with in water, the squaraine showed double absorption peaks (one blue shifted and another red shifted) and absorption intensity of the red shift peak increased with the increase of the time of irradiation.The intensity of the blue one decreased simultaneously. We proposed that the presence of two electronic charge forms of squaraine anchored on the TiO₂ film might be the reason.

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Synthesis,Characterization,Spectroscopic Properties of 2-(4-Dimethylaminophenyl)-5-fluoro-6-(morpholin-4-yl)-1H-benzimidazole and its Interaction with Calf Thymus DNA

Ling Tian TANG, Yi WANG, Xin Qi LIU, Shao Wen HU, Tai Wei CHU, Xiang Yun WANG

中国化学快报. 2005, 16(03): 345-348.

摘要 ( )

可视化

2-(4-Dimethylaminophenyl)-5-fluoro-6-(morpholin-4-yl)-1H-benzimidazole (1) has been synthesized and characterized by ¹H-NMR, MS and elemental analysis. UV-Vis spectra of the aqueous solutions at different pH values reveal that compound 1 can combine three protons. Its three protonation constants are determined by spectrophotometry and calculated by non-linear least squares. The results of steady-state fluorescence measurements indicate that a special interaction occurs between compound 1 and calf thymus DNA, of which the binding constant, K_b, is (2.30±0.10)×l0⁴ L/mol. Compound 1 in the concentration range of 10^-8 to 1.2×l0^-6 mol/L could be used for quantitative determination of DNA.

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Synthesis of Photoactivatable Phospholipidic Probes

Qing PENG, Fan Qi QU, Yi XIA, Jie Hua ZHOU, Qiong You WU, Ling PENG

中国化学快报. 2005, 16(03): 349-352.

摘要 ( )

可视化

We synthesized and characterized photoactivatable phospholipidic probes 1-3. These probes have the perfluorinated aryl azide function at the polar head of phospholipid. They are stable in dark and become highly reactive upon photoirradiation. The preliminary results suggest that they are promising tools to study the topology of membrane proteins and protein-lipid interactions using photolabeling approach.

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A New Isomalabaricane Triterpenoid from Sponge Jaspis sp.

Sheng An TANG, Zhi Wei DENG, Jun LI, Hong Zheng FU, Yue Hu PEI, Si ZHANG, Wen Han LIN

中国化学快报. 2005, 16(03): 353-355.

摘要 ( )

可视化

From the marine sponge Jaspis sp., a new isomalabaricane triterpenoid 22, 23-dihydrostellettin D (1) was isolated, and its structure was established on the basis of IR, MS and extensive 2D NMR spectroscopic analysis. It is a unique skeleton compound rarely obtained from Chinese marine organisms.

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Nanjiols D and E,Two New Uncommon Steroids from the Chinese Soft Coral Nephthea bayeri

Xiao Hong YAN, Yue Wei GUO

中国化学快报. 2005, 16(03): 356-358.

摘要 ( )

可视化

Two new steroids, nanjiols D and E, were isolated from the soft coral Nephthea bayeri.Their structures were characterized by spectroscopic methods and comparison with known compounds.

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A New Saponin Transformed from Ginsenoside Rh_l by Bacillus subtilis

Guo Hong LI, Yue Mao SHEN, Ke Qin ZHANG

中国化学快报. 2005, 16(03): 359-361.

摘要 ( )

可视化

A novel saponin was isolated from the transformed products of ginsenoside Rh1 by Bacillus subtilis. It's structure was determined to be 3-O-β-D-glucopyranosyl-6-O-β-D-glucopyranosyl-20 (S)-protopanaxatriol on the basis of the spectral data.

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Two Cytotoxic Eremophilanolides from Senecio tsoongianus

Qi Jun ZHANG, Hui DOU, Qun Xiong ZHENG, Chang Xin ZHOU, Zhao Jun XU, Hua PENG, Yu ZHAO

中国化学快报. 2005, 16(03): 362-364.

摘要 ( )

可视化

Two new eremophilanolides, tsoongianolide E and F, were isolated from Senecio tsoongianus. Their structures were elucidated on the basis of NMR and MS spectra. Both of these two compounds showed in vitro cytotoxicity to cultured KB and A-549 cancer cell lines.

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Two New Acetylenic Compounds from Asparagus gobicus

Cai Xia YANG, Cheng Shah YUAN, zhong Jian JIA

中国化学快报. 2005, 16(03): 365-366.

摘要 ( )

可视化

Two new acetylenic compounds were isolated from the roots of Asparagus gobicus.Their structures were elucidated by spectroscopic methods including 2D NMR techniques.

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A New Nitro Alkaloid from Corydalis saxicola Bunting

Hui Liang LI, Wei Dong ZHANG, Wei ZHANG, Chuan ZHANG, Run Hui LIU

中国化学快报. 2005, 16(03): 367-368.

摘要 ( )

可视化

A new nitro tetrahydronprotoberberins alkaloid, 1-nitro-apocavidine was isolated from Corydalis saxicola Bunting. The structure was established by spectroscopic methods.

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A New Glucuronidated Metabolite of Andrographolide in Human

Liang CUI, Feng QIU, Nai Li WANG, Xin Sheng YAO

中国化学快报. 2005, 16(03): 369-371.

摘要 ( )

可视化

A new andrographolide metabolite 1 was isolated from human urine samples after oral administration. The structure was determined to be 3-carbonylandrographolide-19-O-β-D-glucuronide on the basis of chemical evidences and spectral analysis, especially by 2D-NMR techniques.

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A Novel Octanuclear Molecular Loop Formed by Linkage of Oxo-centered Triruthenium Cluster Units

Jing Lin CHEN, Li Yi ZHANG, Zhong Ning CHEN

中国化学快报. 2005, 16(03): 372-374.

摘要 ( )

可视化

A novel dimeric complex [Ru₃^Ⅲ,Ⅲ,Ⅱ(μ₃-O)(μ-CH₃COO)(CO)]₂(μ-dppf)(μ-odppf) (dppf=1, l'-bis(diphenylphosphio)ferrocene, odppf=1, 1'-bis(oxodiphenylphosphoranyl)ferrocene) (1) of oxo-centered triruthenium-aectate cluster units was synthesized and characterized by X-ray crystallography. Compound 1 exhibits a cyclic structure formed by linkages of two triruthenium cluster units Ru₃^Ⅲ,Ⅲ,Ⅱ(μ3-O)(μ-CH₃COO)₆(CO) through dppf and odppf ligands, respectively. The diameter of the molecular loop is ca. 1.0 nm.

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Assembling Synthesis of ZnSe Orthohexagonal Slices through Emulsion Liquid Membrane System of Gas-liquid Transport

Lu LIU, Qing Sheng WU, Ya Ping DING, Hua Jie LIU

中国化学快报. 2005, 16(03): 375-378.

摘要 ( )

可视化

Orthohexagonal slices assembled by ZnSe quantum dots were synthesized through emulsion liquid membrane system. These orthohexagonal slices were 1.5-3.5 μm in side length and were self-assembled by ZnSe quantum dots of 2-3 nm. It was proposed the surfactant molecules on ZnSe quantum dots played a key role in the self-assembly process.

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¹H NMR Study of Polyvinylalcohol Irradiated by Ultra-violet

Xiu Ling YAN, Wan Fu SUN, Jun TANG, Xin ZHAO

中国化学快报. 2005, 16(03): 379-381.

摘要 ( )

可视化

The effect of Ultra-violet light on the structure and motion of the polyvinyl alcohol(PVA) chains was studied by ¹H NMR, spin-lattice relaxation and IR spectroscopy. The results indicated that with the increase of irradiation time, the intensity of the polymer hydroxyl proton peaks decreased and finally vanished, which suggested the self-condensation between the hydroxyl groups proceeded. No methyl proton peaks appeared in the spectra after irradiation shows that there is no cleavage of polymer chain. The longer the irradiation time is, the wider the proton peak of the residual water of the solvent is and it shifted toward low field. This result implies that the hydrogen bonds formed between the polymer and the residual water. The absorption peak of hydroxyl group of the polymer moves toward the lower wave number in the IR spectrum that showed the existence of the hydrogen bonds between the PVA macromolecules.

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Electrochemical Studies of the Recognition Interaction of Rhodamine B with DNA

Kui JIAO, Qing Jun LI, Wei SUN, Zhen Yong WANG

中国化学快报. 2005, 16(03): 382-384.

摘要 ( )

可视化

The recognition interaction of rhodamine B (RB) with DNA was studied in pH 7.5 Britton-Robinson (B-R) buffer solution by electrochemical techniques. An irreversible oxidation peak at glassy carbon electrode was obtained at +0.92 V (vs.SCE). After the addition of DNA into the RB solution, the peak current of RB decreased apparently without the shift of peak potential. The electrochemical parameters such as the charge transfer coefficient α and the electrode reaction standard rate constant k_s of RB in the absence and presence of DNA were determined, which did not change, indicating that a non-electroactive complex was formed, so the concentration of RB in the solution decreased and the peak current decreased correspondingly.

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³¹P NMR and ESI-MS Studies on Some Intermediates of the Peptide Coupling Reagents Triphenyl-chlorophosphoranes

Guo TANG, Gui Ji ZHOU, Feng NI, Li Ming HU, Yu Fen ZHAO

中国化学快报. 2005, 16(03): 385-388.

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可视化

The intermediates of the Appel coupling reagents were studied in acetonitrile,dimethoxyethane and dioxane by ³¹P NMR,¹³C NMR spectrum and ESI-MS. In dioxane a new high coordinated phosphorous compound with ³¹P NMR shift at -39 ppm was observed. The ESI-MS showed that it could be a penta-coordinated phosphorous compound containing dioxane. The carboxyl activated intermediates were also studied in three solvents.

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Refolding with Simultaneous Purification of Recombinant Human Granulocyte Colony-stimulating Factor from Escherichia coli Using Strong Anion Exchange Chromatography

Chao Zhan WANG, Jiang Feng LIU, Xin Du GENG

中国化学快报. 2005, 16(03): 389-392.

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可视化

The urea denatured recombinant human granulocyte colony-stimulating factor (rhGCSF) which was expressed in Escheriachia coli (E. coli) was refolded with simultaneous purification by strong anion exchange chromatography (SAX) in the presence of low concentration of urea. The effect of urea concentration on this refolding process was investigated. The obtained refolded rhG-CSF has a high specific activity of 2.3×10⁸ U/mg, demonstrating that the proteins were completely refolded during the chromatographic process. With only one step by SAX in 40 min, purity and mass recovery of the refolded and purified rhG-CSF were 97% and 43%, respectively.

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A Model-based Phenomenological Investigation of Char Combustion Kinetics through Thermogravimetry

Qun CHEN, Rong HE, Zhan Gang LIANG, Xu Chang XU, Chang He CHEN

中国化学快报. 2005, 16(03): 393-396.

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可视化

Five coal char samples were burnt in thermobalance with ramp heating rate of 30 K/min.The pore structure of these char samples was studied through mercury intrusion method.Combined with the kinetic theory of gases, the data of surface area was used in fitting the results.As a result, the kinetic triplet was given. The analysis showed that five char samples share almost the same intrinsic activation energy of the overall reaction. The phenomenological implication of the derived combustion rate equation was given.

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In situ Synthesis of Oligonucleotides on Plasma Treated Polypropylene Microporous Membrane

Nong Yue HE, Jian Xin TANG, Song LI, Hong CHEN, An Cun ZHOU

中国化学快报. 2005, 16(03): 397-400.

摘要 ( )

可视化

Polypropylene microporous membranes were treated with plasma in a mixture of N₂ and H₂ (1:2 in volume). Attenuated total reflectance Fourier transform infrared spectroscopy (ATR-FTIR), X-ray photoelectron spectroscopy (XPS) and ultra-violet (UV) spectra demonstrated the success of grafting amino groups. The density of the polar amino groups on the membrane surface is about 0.59 μmol/cm². The as-treated membranes were successively applied to the in situ synthesis of oligonucleotides and an average coupling yield was more than 98%. The surface feature of the treated membrane is suggested to be responsible for its advantage over a glass slide.

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Synthesis and Properties of Polyurethane Resins from Liquefied Benzylated Wood

Yu Ping WEI, Fa CHENG, Hou Ping LI, Jiu Gao YU

中国化学快报. 2005, 16(03): 401-404.

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可视化

In this paper, polyurethane resins were synthesized from liquefied benzylated wood and TDI (toluene diisocyanate)-TMP (trihydromethylene propane) prepolymer. And the relation between microphase structure and properties of PU samples were also studied. The results indicated that coatings obtained had good mechanical and thermal properties. The amount of the curing agent has great effect on the degree of phase segregation. In addition, with increased the curing agent amount, the thermal stabilities were also improved.

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Synthesis and Fluorescence of alt-Copoly[1,4-divinylenebenzene/1,4-bis(dimethylsilylene)benzene]

Xiao Bang DUAN, Guo Ping CAI, William P. WEBER, Ping LU

中国化学快报. 2005, 16(03): 405-408.

摘要 ( )

可视化

Silicon inserted π conjugated copolymer was synthesized by Heck reaction with moderate molecular weight. This silicon containing copolymer is thermally stable to 400℃, while emission of this polymer is blue-shifted compared with polyphenylenevinylene greenish emission. It shows potential application as organic emitter in OLED.

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Irradiation Initiated Grafting of Poly(butyl acrylate) onto Nano-sized Calcium Carbonate Particles

Chuan Guo MA, Min Zhi RONG, Ming Qiu ZHANG

中国化学快报. 2005, 16(03): 409-412.

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可视化

The present work reports the irradiation induced grafting polymerization onto nano-sized CaCO₃ particles, mainly focusing on the effects of pretreatment with silane coupling agent. It is proved that poly(butyl acrylate) can be grafted onto the nanoparticles using the technical route suggested by the authors, and the silane treatment of the nanoparticles promotes the grafting polymerization.

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Synthesis and Separating Performance of SAPO-44 Zeolite Membrance

Zan LIU, Zhi Lin CHENG

中国化学快报. 2005, 16(03): 413-415.

摘要 ( )

可视化

A defect-free SAPO-44 zeolite membrane firmly anchored the porous α-Al₂O₃ plate substrate was successfully synthesized. The separating results showed that the H₂/N₂ and H₂/CO permselectivities were higher than those of the corresponding Knudsen diffusion and the substrate,attaining 5.78 and 7.15 respectively.

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An Integrated DNA Modified Dual-microelectrode Sensor Probe

Xiang Qin LIN, Li Ping LU, Xiao Hua JIANG

中国化学快报. 2005, 16(03): 416-418.

摘要 ( )

可视化

A unique method for preparing a coaxial dual-microelectrode sensor by vaporizing the nano-thickness Au layer on the DNA modified carbon fiber micro-column electrode was illustrated.The dual-electrode showed particular merit for determination in biological systems.

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Determination of Proton Diffusion Coefficient in Spherical Nickel Hydroxide Using Potential Step Measurement on Single Beads

Liang XIAO, Jun Tao LU, Pei Fang LIU, Lin ZHUANG, Jia Wei YAN, Rong Gang HU, Bing Wei MAO, Chang Jian LIN

中国化学快报. 2005, 16(03): 419-422.

摘要 ( )

可视化

The Potential step measurements are carried out on single beads of nickel hydroxide and the results are interpreted with a dual structure model featuring fast and slow diffusing components.The intrinsic diffusion coefficients for the two components are found to be in the order of magnitude 10^-7 and 10^-13~10^-14 cm²s^-1, respectively, with an apparent value for the slow component in the order of 10^-10 cm²s^-1.

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A Novel Pyrazoline-based Starburst Amorphous Molecular Material

Yi Shan YAO, Xue Song WANG, Bao Wen ZHANG, Yi CAO, Chang Qi MA

中国化学快报. 2005, 16(03): 423-426.

摘要 ( )

可视化

A pyrazoline-containing starburst molecule, 4,4',4"-tris[(1,3-diphenyl-4,5-dihydro-1Hpyrazol)-5-yl]-triphenylamine (Tris-5-DPP), was synthesized in a facile way, which can form amorphous thin films with glass transition temperature as high as 136℃.

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2005年, 第16卷, 第03期　刊出日期：2005-03-20

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本期目录

2005年, 第16卷, 第03期 刊出日期：2005-03-20

2005年, 第16卷, 第03期　刊出日期：2005-03-20