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 Efficient Synthesis of the C1-C7 Fragment of Didemnaketal A
Xue Qiang LI, Xue Zhi ZHAO, Pei Nian LIU, Yong Qiang TU
Chinese Chemical Letters 2004;15;07:757-758

 Efficient Synthesis of the C1-C7 Fragment of Didemnaketal A
Xue Qiang LI, Xue Zhi ZHAO, Pei Nian LIU, Yong Qiang TU
Chinese Chemical Letters, 2004; 15: 757-758
The stereoselective synthesis of the C1-C7fragment (3R,4S,6R)-3,4-di[(tert-butyl-dimethylsilyl)oxy]-7-hydroxy-6-methylheptan-2-one, which is the crucial intermediate for synthesis of the HIV-1 protease inhibitive didemnaketals, was developed via 12 steps from the natural (+)-pulegone.
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