|
|
|
| Mn(OAc)2/Schiff base as a new efficient catalyst system for the Henry reaction of nitroalkanes with aldehydes |
| Guang Peng Zhou , Yong Hai Hui , Ning Ning Wan , Qiu Ju Liu , Zheng Feng Xie *, Ji De Wang * |
| Key Laboratory of Oil and Gas Fine Chemicals, Ministry of Education and Xinjiang Uyghur Autonomous Region, College of Chemistry and Chemical Engineering, Xinjiang University, Urumqi 830046, China |
|
|
|
|
Abstract A series of novel Schiff bases bearing triazole structure were synthesized and characterized by IR and NMR. Mn(OAc)2/Schiff base efficiently catalyzed Henry reaction of nitroalkanes with aldehydes to produce the corresponding products of β-nitroalcohols, under mild conditions with high yields (up to 99 %). A reaction mechanism is proposed based on the experimental results.
|
|
|
|
|
|
|
|
|
