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| Transition metal coordinated framework porphyrin for electrocatalytic oxygen reduction |
| Chang-Xin Zhaoa, Bo-Quan Lia, Jia-Ning Liua, Jia-Qi Huangb, Qiang Zhanga |
a Beijing Key Laboratory of Green Chemical Reaction Engineering and Technology, Department of Chemical Engineering, Tsinghua University, Beijing 100084, China;
b Advanced Research Institute of Multidisciplinary Science, Beijing Institute of Technology, Beijing 100081, China |
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| Guide A series of transition metal coordinated framework porphyrin was evaluated regarding the electrocatalytic oxygen reduction reactivity for an optimized selection of the coordinated metal ion. |
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Abstract Oxygen reduction reaction (ORR) constitutes the core process of many clean and sustainable energy systems including fuel cells and metal-air batteries. Developing high-performance and cost-efficiency ORR electrocatalysts is of great significance to the practical applications of the above-mentioned energy storage devices. Transition metal coordinated porphyrin electrocatalysts are highly considered as a promising substitution of noble-metal-based electrocatalyst because of their high ORR reactivity, where the ORR performances of the porphyrin-based electrocatalysts are highly dependent on the transition metal center. Herein a series of framework porphyrin electrocatalysts coordinated with different transition metal centers (M-POF, where M is Mn, Fe, Co, Ni, Cu, or Zn) was designed, synthesized, and evaluated in regards of electrocatalytic ORR performances. Among all, the Co-POF electrocatalyst exhibits the best ORR performances with the highest half-wave potential of 0.81 V vs. RHE and the lowest Tafel slope of 53 mV/dec. This contribution affords an optimized high-performance ORR electrocatalyst and provides instructions for further rational design of porphyrin-based ORR electrocatalysts for sustainable energy applications.
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Received: 07 March 2019
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| Fund:This work was supported by National Key Research and Development Program (Nos. 2016YFA0202500 and 2016YFA0200102), National Natural Science Foundation of China (No. 21825501), and Tsinghua University Initiative Scientific Research Program. |
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