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| Solvent and additive-free selective aerobic allylic hydroxylation of β-pinene catalyzed by metalloporphyrins |
| Shi-Chao Xua,b,c,d,e,f, Shou-Ji Zhua,b,c,d, Liang-Wu Bia,b,c,d,e,f, Yu-Xiang Chena,b,c,d,e, Jing Wanga,b,c,d, Yan-Ju Lua,b,c,d,e, Yan Gua,b,c,d, Zhen-Dong Zhaoa,b,c,d,e,f |
a Institute of Chemical Industry of Forest Products, Chinese Academy of Forestry, Nanjing 210042, China;
b Key Lab. of Biomass Energy and Material, Jiangsu Province, Nanjing 210042, China;
c National Engineering Lab. for Biomass Chemical Utilization, Nanjing 210042, China;
d Key and Open Lab. on Forest Chemical Engineering, State Forestry Administration, Nanjing 210042, China;
e Institute of Forestry New Technology, Chinese Academy of Forestry, Beijing, 100091, China;
f 2011 Collaborative Innovation Center of Jiangxi Typical Trees Cultivation and Utilization in Jiangxi Agricultural University, Nanchang, 330045, China |
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Abstract Metallodeuteroporphyrins (MDPs) were employed as the catalysts for aerobic oxidation of β-pinene in absence of solvents and additives. Allylic hydroxylation products were found to be the main products from this protocol. The catalytic activity of MDPs with different metal nuclei and the influences of technological conditions on this reaction were investigated. This catalytic system has bright application prospect since only eco-friendly and readily available dioxygen were needed.
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Received: 10 October 2016
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| Fund:This work was funded by the Fundamental Research Funds for Jiangsu Key Lab of Biomass Energy and Material (No. JSBEM-S-201605), the National Natural Science Foundation of China (No. 31600466) and the Fundamental Research Funds for the Central Non-profit Research Institution of CAF (No. CAFYBB2014QA022). |
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Corresponding Authors:
Zhen-Dong Zhao
E-mail: zdzhao@189.cn
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