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| A colorimetric and ratiometric fluorescent chemosensor based on furan-pyrene for selective and sensitive sensing Al3+ |
| Yuan Zhanga, Yuan Fanga, Nai-Zhang Xua, Ming-Qun Zhanga, Guan-Zhi Wuc, Cheng Yaoa,b |
a College of Chemistry and Molecular Engineering, Nanjing Tech University, Nanjing 211816, China;
b State Key Laboratory of Coordination Chemistry, Nanjing University, Nanjing 210093, China;
c College of Overseas Education, Nanjing Tech University, Nanjing 211816, China |
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Abstract A new pyrene derivative BF bearing a furan group was synthesized via a one-step reaction as a colorimetric and ratiometric chemosensor for Al3+in ethanol-H2O (9:1,v/v,pH 7.2,HEPES buffer) solution.This chemosensor could selectively recognize Al3+ in the presence of other competing ions.Low limit of detection (LOD) and high association constant revealed its superior sensitivity and binding affinity toward Al3+.Besides,the probe BF performed perfectly in a reversibility test using EDTA.The mechanism of the interaction has been confirmed by 1H NMR titration.Importantly,chemosensor BF has also been utilized to detect Al3+ on test paper strips,which showed its potential for practical applications.
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Received: 08 March 2016
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Corresponding Authors:
Cheng Yao
E-mail: yaocheng@njtech.edu.cn,yaochengnjut@126.com
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