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| Low-temperature hydrogenation of maleic anhydride to succinic anhydride and γ-butyrolactone over pseudo-boehmite derived alumina supported metal (metal = Cu, Co and Ni) catalysts |
| Jie Li, Lin-Ping Qian, Li-Ya Hu, Bin Yue, He-Yong He |
| Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, China |
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Abstract The pseudo-boehmite derived alumina supported metal (Cu, Co and Ni) catalysts prepared by the impregnation method were investigated in hydrogenation of maleic anhydride (MA) to succinic anhydride (SA) and γ-butyrolactone. The catalysts were characterized by ICP-AES, N2 adsorption-desorption, XRD, H2-TPR, CO-TPD, dissociative N2O adsorption and TEM and the results showed that the alumina possessed mesoporous feature and the metal species were well dispersed on the support. Compared to Cu/Al2O3 and Co/Al2O3, Ni/Al2O3 exhibited higher catalytic activity in the MA hydrogenation with 92% selectivity to SA and nearly 100% conversion of MA at 140 ℃ under 0.5 MPa of H2 with a weighted hourly space velocity of 2 h-1 (MA). The stability of Ni/Al2O3 catalyst was also investigated.
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Received: 15 February 2016
Published: 19 March 2016
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| Fund:This work was supported by the National Natural Science Foundation of China (Nos. 21173050 and 21371035) and China Petrochemical Corporation (No. X514005). |
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Corresponding Authors:
Bin Yue, He-Yong He
E-mail: yuebin@fudan.edu.cn;heyonghe@fudan.edu.cn
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