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Synthesis and electrochemical properties of Li1-xVxCryFe1-yPO4/C as a cathode material |
Shi Tao Songa,b, Pei Hua Maa, Shi You Lia,b, Xiao Chuan Denga, Chun Yan Yana,b |
a Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008, China; b Graduate School of the Chinese Academy of Sciences, Beijing 100039, China |
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Abstract Composites Li1-xVxCryFe1-yPO4/C (x=0.01, 0.02; y=0.01, 0.02) were synthesized by solid-state reaction method. The influence of the content of doping vanadium and chromium on the structure of Li1-xVxCryFe1-yPO4/C was investigated by XRD, while the morphology of powders was observed by SEM. The investigation of the electrochemical performances showed that the Li0.99V0.01Cr0.02Fe0.98PO4/C material has a higher capacity. At 0.1 C discharging rate, it is capable of delivering reversible specific capacity of 163.8 mAh/g with fairly stable cycleability.
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Received: 27 August 2007
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Fund:This work was supported by the National Key Technologies R&D Program of China during the 10th Five-Year Plan Period (No. 2004BA602B-01) and Science and Technology Foundation of Qinghai Province (No. 2006-G-168). |
Corresponding Authors:
Shi Tao Song,E-mail address:sst1210@163.com
E-mail: sst1210@163.com
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