|
|
|
| Inhibitory effect of H3+xPMo12-xVxO40-T on the self-polymerization of methyl methacrylate |
| Yan-Bing Yina, Hui-Song Wanga, Yu-Lin Yangb, Rui-Qing Fanb, Guo-Hua Donga,b, Li-Guo Weic |
a College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar 161006, China;
b Department of Chemistry, Harbin Institute of Technology, Harbin 150001, China;
c College of Environmental and Chemical Engineering, Heilongjiang University of Science and Technology, Harbin 150022, China |
|
|
|
|
Abstract In this work, a series of molybdovanadophosphoric heteropoly acid quaternary ammonium salts (H3+xPMo12-xVxO40-T) were synthesized and employed as a reaction inhibitor in the selfpolymerization of methyl methacrylate (MMA). The polymerization inhibition effect of H3+xP-Mo12-xVxO40-T with different number of vanadium atoms and reaction dosages was investigated using differential scanning calorimetry (DSC). It shows that the inhibitory effect was improved with the increasing dosages of H3+xPMo12-xVxO40-T, and the polymerization inhibition was also affected by the number of vanadium atoms in the H3+xPMo12-xVxO40-T. Furthermore, cyclic voltammograms (CV) was used to probe the mechanism of the inhibition reaction with H3+xPMo12xVxO40-T. The result of CV indicates that the inhibition reaction is an oxidation-reduction reaction. H3+xPMo12-xVxO40-T can react directly with the MMA monomer radicals, which eliminated the MMA monomers, and therefore the self-polymerization of the MMA can be effectively inhibited by H3+xPMo12-xVxO40-T.
|
|
Received: 10 January 2016
Published: 23 February 2016
|
| Fund:This work was supported by the Research and Development Fund for the postdoctoral researchers of Heilongjiang Province (2012). |
|
Corresponding Authors:
Yan-Bing Yin, Yu-Lin Yang
E-mail: yinyanbing70@163.com;ylyang@hit.edu.cn
|
|
|
|
| [1] |
Y.J. Chang, X.Z. Liu, Q. Zhao, et al., P(VPBA-DMAEA) as a pH-sensitive nanovalve for mesoporous silica nanoparticles based controlled release, Chin. Chem. Lett. 26(2015) 1203-1208.
|
| [2] |
F. Cilurzo, F. Selmin, C.G.M. Gennari, L. Montanari, P. Minghetti, Application of methyl methacrylate copolymers to the development of transdermal or locoregional drug delivery systems, Expert Opin. Drug Deliv. 11(2014) 1033-1045.
|
| [3] |
F. Deng, X. Ge, Y.H. Zhang, M.C. Li, U.R. Cho, Synthesis and characterization of microcrystalline cellulose-graft-poly(methyl methacrylate) copolymers and their application as rubber reinforcements, J. Appl. Polymer Sci. 132(2015) 42666.
|
| [4] |
J.O. Fajemiroye, P.R. Polepally, N.D. Chaurasiya, et al., Oleanolic acid acrylate elicits antidepressant-like effect mediated by 5-HT1A receptor, Sci. Rep. 5(2015) 11582.
|
| [5] |
T. Fukuda, Y.D. Ma, H. Inagaki, Free-radical copolymerization. 3. Determination of rate constants of propagation and termination for styrene/methyl methacrylate system.Acritical test of terminal-model kinetics,Macromolecules 18(1985) 17-26.
|
| [6] |
D.M. Haddleton, C.B. Jasieczek, M.J. Hannon, A.J. Shooter, Atom transfer radical polymerization of methyl methacrylate initiated by alkyl bromide and 2-pyridinecarbaldehyde imine copper(I) complexes, Macromolecules 30(1997) 2190-2193.
|
| [7] |
K. Matyjaszewski, M.L. Wei, J.H. Xia, N.E. McDermott, Controlled/"living" radical polymerization of styrene and methyl methacrylate catalyzed by iron complexes, Macromolecules 30(1997) 8161-8164.
|
| [8] |
H.X. Jin, Q.Y. Wu, P. Zhang, W.Q. Pang, Assembling of tungstovanadogermanic heteropoly acid into mesoporous molecular sieve SBA-15, Solid State Sci. 7(2005) 333-337.
|
| [9] |
M. Kato, M. Kamigaito, M. Sawamoto, T. Higashimura, Polymerization of methyl methacrylate with the carbon tetrachloride/dichlorotris-(triphenylphosphine) ruthenium(II)/methylaluminum bis(2, 6-di-tert-butylphenoxide) initiating system-possibility of living radical polymerization, Macromolecules 28(1995) 1721-1723.
|
| [10] |
G.X. Wang, W.B. Xu, Q. Hou, S.W. Guo, A simple sonochemical method for fabricating poly(methyl methacrylate)/stearic acid phase change energy storage nanocapsules, Ultrason. Sonochem. 27(2015) 403-407.
|
| [11] |
B. Gumgum, O. Akba, A. Baysal, C. Hamamci, Synthesis and characterization of polyoxometallate compounds of amine and phosphine with molybdovanadophosphoric acid in Keggin type, Asian J. Chem. 18(2006) 1862-1866.
|
| [12] |
S.V. Mayani, V.J. Mayani, S.W. Kim, Synthesis of molybdovanadophosphoric acid supported hybrid materials and their heterogeneous catalytic activity, Mater. Lett. 111(2013) 112-115.
|
| [13] |
V.F. Odyakov, E.G. Zhizhina, R.I. Maksimovskaya, Synthesis of molybdovanadophosphoric heteropoly acid solutions having modified composition, Appl. Catal. A General 342(2008) 126-130.
|
| [14] |
W.L. Yang, L.Y. Wang, Q.W. Wang, Synthesis and antibacterial property of heteropoly acid quaternary ammonium salt antimicrobial agent with double active center, Chin. J. Inorg. Chem. 29(2013) 295-302.
|
| [15] |
J. Alcañiz-Monge, G. Trautwein, M.C. Romań-Martínez, Effect of counteranion of ammonium salts on the synthesis of porous nanoparticles (NH4)3[PMo12O40], Solid State Sci. 13(2011) 30-37.
|
| [16] |
L. Cheng, X.M. Zhang, X.D. Xi, B.F. Liu, S.J. Dong, Electrochemical behavior of the molybdotungstate heteropoly complex with neodymium, K10H3[Nd(SiMo7-W4O39)2]·xH2O in aqueous solution, J. Electroanal. Chem. 407(1996) 97-103.
|
| [17] |
P. Villabrille, G. Romanelli, L. Gassa, P. Vázquez, C. Cáceres, Synthesis and characterization of Fe- and Cu-doped molybdovanadophosphoric acids and their application in catalytic oxidation, Appl. Catal. A General 324(2007) 69-76.
|
| [18] |
N. Li, R. Chen, J. Miao, et al., Synthesis of single crystal-like hierarchically mesoporous titanosilicate Ti-SBA-1, Chin. Chem. Lett. 26(2015) 1269-1272.
|
| [19] |
H. Wang, Y.P. Chen, Z.C. You, et al., Synthesis and characterization of a new catalyst for RhB degradation constructed by[SiMo12O40]4- anionic cluster, Chin. Chem. Lett. 26(2015) 187-192.
|
| [20] |
R. Pingaew, S. Prachayasittikul, S. Ruchirawat, V. Prachayasittikul, Tungstophosphoric acid catalyzed synthesis of N-sulfonyl-1,2,3,4-tetrahydroisoquinoline analogs, Chin. Chem. Lett. 24(2013) 941-944.
|
| [21] |
Y.B. Yin, Y.L. Yang, R.Q. Fan, Y.Q. Zhu, J.R. Sun, Synthesis, characterization and inhibition effects of vanadium substituted Dawson-type heteropoly acids (Mo. P), Chem. Res. Chin. Univ. 27(2011) 358-360.
|
| [22] |
Y. Chen, X.L. Zhang, X. Chen, B.B. Dong, X.C. Zheng, MCM-41 supported 12-tungstophosphoric acid mesoporous materials:preparation, characterization, and catalytic activities for benzaldehyde oxidation with H2O2, Solid State Sci. 24(2013) 21-25.
|
| [23] |
J.X. Wang, J.J. Wu, H. Chen, S.W. Zhang, F.H. Wu, Synthesis of difluoroalkyl-γ-butyrolactones from iododifluoromethyl ketones and 4-pentenoic acids, Chin. Chem. Lett. 26(2015) 1381-1384.
|
| [24] |
D.M. Fernandes, A. Teixeira, C. Freire, Multielectrocatalysis by layer-by-layer films based on pararosaniline and vanadium-substituted phosphomolybdate, Langmuir 31(2015) 1855-1865.
|
| [25] |
W. Zhu, W.J. Zhang, S. Li, et al., Fabrication and electrochemical sensing performance of a composite film containing a phosphovanadomolybdate and cobalt(II) tetrasulfonate phthalocyanine, Sens. Actuators B Chem. 181(2013) 773-781.
|
|
|
|
