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A cucurbit[8]uril recognized rigid supramolecular polymer with photo-stimulated responsiveness |
Tian-Tian Cao, Xu-Yang Yao, Jing Zhang, Qiao-Chun Wang, Xiang Ma |
Key Laboratory for Advanced Materials and Institute of Fine Chemicals, East China University of Science and Technology, Shanghai 200237, China |
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Guide A photo-responsive rigid supramolecular polymer was constructed via cucurbit[8]uril recognition with a rigid monomer containing azobenzene and 4,4-bipyridin-1-ium moieties |
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Abstract A rigid supramolecular polymer was constructed in aqueous solution via cucurbit[8]uril (CB[8]) host recognition with a rigid monomer containing an azobenzene unit and two 4,40-bipyridin-1-ium (BP) moieties in the two ends, which also exhibited photo-responsiveness owing to the photoinduced transcis isomerization of azobenzene group.
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Received: 05 December 2014
Published: 07 February 2015
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Fund: This work was financially supported by NNSFC (Nos. 21190033, 21272072, 21476075 and 21372076), the National Basic Research 973 Program (No. 2011CB808400), the Shanghai Pujiang Program (No. 13PJD011) and the Fundamental Research Funds for the Central Universities. |
Corresponding Authors:
Qiao-Chun Wang, Xiang Ma
E-mail: qcwang@ecust.edu.cn;maxiang@ecust.edu.cn
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