Comparative studies on molecular induced aggregation of hepta-imidazoliumyl-β-cyclodextrin towards anionic surfactants
Di Zhao, Yong Chen, Yu Liu
Department of Chemistry, State Key Laboratory of Elemento-Organic Chemistry, Nankai University, Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin 300071, China
Guide A new beta-cyclodextrin derivatives with seven cationic arms was synthesized, giving good induced aggregation effects towards anionic surfactants.
Abstract
A b-cyclodextrin derivative bearing seven cationic arms and its singly charged analogue, i.e., per-6- deoxy-6-(1-methylimidazol-3-ium-3-yl)-β-cyclodextrin (3) and mono-6-deoxy-6-(1-methylimidazol-3-ium-3-yl)-β-cyclodextrin (4) were synthesized and fully characterized. Their induced aggregation behaviours towards two anionic surfactant, that is, sodium dodecyl sulfonate (SDS) and dioctyl sodium sulfosuccinate (Aerosol OT, AOT), were investigated by UV-vis, NMR, Zeta-potential, dynamic light scattering (DLS), and transmission electron microscopy. The results revealed that host 3 can induce the molecular aggregation of anionic surfactant at concentration far lower than its original CAC, leading to the larger diameter, the narrower size distribution and the higher thermal stability of the induced aggregate towards the anionic surfactant possessing more hydrophobic tails.
Received: 29 September 2014
Published: 25 November 2014
Fund:
We thank 973 Programme (No. 2011CB932502) and NNSFC (Nos. 91227107, 21432004, and 21272125) for financial support.
Corresponding Authors:
Yu Liu
E-mail: yuliu@nankai.edu.cn
