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| A BODIPY analogue from the tautomerization of sodium 3-oxide BODIPY |
| Peng-Zhong Chena,b, Hai-Rong Zhenga,b, Li-Ya Niua, Yu-Zhe Chena, Li-Zhu Wua, Chen-Ho Tunga, Qing-Zheng Yanga,c |
a Key Laboratory of Photochemical Conversion and Optoelectronic Materials, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China;
b University of the Chinese Academy of Sciences, Beijing 100049, China;
c College of Chemistry, Beijing Normal University, Beijing 100875, China |
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Abstract The introduction of hydroxy group to the 3-or 5-position of 4,4-difluoro-4-bora-3a,4a-diazaindacene (BODIPY) results in unexpected tautomerization to BDPONa with interesting structural and photophysical properties. The core of BDPONa is an anion with sodium cation as counter-ion. BDPONa displays strong fluorescence in organic solvents.
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Received: 13 March 2015
Published: 18 April 2015
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| Fund: This work was financially supported by the 973 program (Nos. 2013CB933800, 2013CB834505), National Natural Science Foundation of China (Nos. 21222210, 21102155, 91027041), and the Chinese Academy of Sciences (100 Talents Program). |
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Corresponding Authors:
Qing-Zheng Yang
E-mail: qzyang@mail.ipc.ac.cn
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